This is the first report that an appropriate temperature gradient play
s a catalytic role in the growth of Bi-system whiskers. Pi-system whis
kers are grown out only under a temperature gradient of 2-5 degrees C/
cm, but not under other cases. The fact strongly supports the tip grow
th mechanism. Magnetization measurement and four probe resistance meas
urement show that these whiskers have perfect superconducting properti
es.