Zy. Chen et al., SYNTHESIS OF NEW PRASEODYMIUM-BASED CUPRATES (PR,CD)SR(2)YCU(2)OY AND(PR,M)SR-2(GD,CE)(2)CU2OZ (M=CU,ZN), Physica. C, Superconductivity, 282, 1997, pp. 805-806
Two new families of praseodymium-based cuprates, (Pr,Cd)Sr2YCu2Oy and
(Pr,M)Sr-2(Gd,Ce)(2)Cu2Oz (M = Cu,Zn), have been synthesized and ident
ified by XRD, ED analyses. (Pr,Cd)-1212 crystallizes in a orthorhombic
cell, with a = 3.838 Angstrom, b = 3.812 Angstrom, c = 11.82 Angstrom
, (Pr,M)-1222 is of a tetragonal cell with a = 3.837 Angstrom, c = 28.
799 Angstrom for (Pr0.5Cu0.5)Sr-2(Gd1.2Ce0.8)Cu2Oz and a = 3.824 Angst
rom, c = 28.990 Angstrom for (Pr0.5Zn0.5)Sr-2(Gd1.2Ce0.8)Cu2Oz. Their
ED patterns show that no superstructure exists in the two series of Pr
-based cuprates. These compounds are semiconductors under the present
experimental conditions.