T. Frello et al., DYNAMICS OF OXYGEN ORDERING IN YBA2CU3O6-ENERGY SYNCHROTRON X-RAY-DIFFRACTION(X STUDIED BY NEUTRON AND HIGH), Physica. C, Superconductivity, 282, 1997, pp. 1089-1090
The dynamics of the ortho-II oxygen structure in a high purity YBa2Cu3
O6+x, single crystal with x=0.50 has been studied by neutron and by X-
ray diffraction with a photon energy of 100 keV. Our data show that th
e oxygen order develops on two different time-scales, one of the order
of seconds and a much slower of the order of weeks and months. The me
chanism dominating the slow time-scale is related to oxygen diffusion,
while the fast mechanism may result from a temperature-dependent chan
ge in the average oxygen chain length.