STERIC CONTROL IN THE SYNTHESIS OF TRANS-(1-ALPHA-H 5-BETA-OH)-3,10-GUAIADIEN-6,12-OLIDE

Authors
KESTERNICH V MARTINEZ R
Citation
V. Kesternich et R. Martinez, STERIC CONTROL IN THE SYNTHESIS OF TRANS-(1-ALPHA-H 5-BETA-OH)-3,10-GUAIADIEN-6,12-OLIDE, Boletin de la Sociedad Chilena de Quimica, 42(3), 1997, pp. 401-403
Citations number
5
Categorie Soggetti
Chemistry
Journal title
Boletin de la Sociedad Chilena de Quimica → ACNP
ISSN journal
03661644
Volume
42
Issue
3
Year of publication
1997
Pages
401 - 403
Database
ISI
SICI code
0366-1644(1997)42:3<401:SCITSO>2.0.ZU;2-S
Abstract
The first biomimetic synthesis of trans-(1 alpha-H;5 beta-OH)-3,10-gua iadien-6,12-olide was possible via allylic induction over the epoxidat ion as key step. The starting material was alpha-santonin, an eudesman olide.