The emission spectrum measured on the reversed field pinch RFX is domi
nated by carbon and oxygen lines. Nickel lines are seldom observed eve
n though a large magnetic field perturbation causes intense plasma-wal
l interaction. The line emissions from hydrogen-like and helium-like i
ons observed in RFX are simulated by a collisional-radiative impurity
diffusion model. An impurity diffusion coefficient of the order of 10
m(2)/s and an inward convective velocity of 90 m/s have been used for
an adequate simulation of the hydrogen-like to helium-like resonant li
ne ratios. The model can be used to estimate the effective charge of t
he plasma; the on-axis values in 800 kA discharges are found to range
between 1.5 and 2.2, with peaks higher than 3 in the presence of carbo
n blooms. It is found that charge exchange processes with thermal hydr
ogen neutral atoms must be considered to account for the high G ratio
values measured for carbon (0.6 to 0.7).