HYDROLOGICAL CONTROLS ON COPPER, CADMIUM, LEAD AND ZINC CONCENTRATIONS IN AN ANTHROPOGENICALLY POLLUTED MANGROVE ECOSYSTEM, WYNNUM, BRISBANE, AUSTRALIA

Biogenic sulphides, particularly pyrite and hydrated iron-monosulphide s, are common in sediments in mangrove ecosystems where they may provi de a geochemical trap for heavy metals. However, oxidation of the sulp hides can lead to remobilisation of metallic species and the developme nt of acid sulphate soil conditions. In this paper the effects of prol onged dry conditions on the metal binding capacity of sediments in a m angrove forest are investigated. Data from 1989 show that the mangrove forest is acting as a buffer between a domestic garbage tip and the o pen waters of Moreton Bay. However, prolonged dry conditions during 19 91 removed much of this buffering capacity and some metals were mobili sed to deeper layers in the sediment or transported down the hydraulic gradient until chemical conditions more favourable for metal trapping were encountered This study shows that understanding the transient na ture of geochemical conditions in natural environments is important in environmental management because: (a) consideration needs to be given to how environmental data collected at one time may be affected by na tural changes (commonly cyclic) in geochemical conditions; (b) conside ration needs to be given to how human activities may have affected nat ural changes in geochemical conditions; and (c) planned development or environmental remediation work will need to anticipate the consequenc es of natural changes in geochemical conditions.