Five absorption features are reported at wavelengths of 3.4, 3.88, 4.0
5, 4.25, and 4.57 micrometers in the surface materials of the Galilean
satellites Callisto and Ganymede from analysis of reflectance spectra
returned by the Galileo mission near-infrared mapping spectrometer. C
andidate materials include CO2, organic materials (such as tholins con
taining C=N and C-H), SO2, and compounds containing an SH-functional g
roup; CO2, SO2, and perhaps cyanogen [(CN)(2)] may be present within t
he surface material itself as collections of a few molecules each. The
spectra indicate that the primary surface constituents are water ice
and hydrated minerals.