A NEW TETRAAZAMACROCYCLE FUNCTIONALIZED WITH PENDANT PYRIDYL GROUPS -SYNTHESIS AND CRYSTAL-STRUCTURE OF A COPPER(II) COMPLEX OF IS(2-PYRIDYLMETHYL)-1,4,7,10-TETRAAZACYCLODODECANE (L), [CUL]CENTER-DOT(CLO4)(2)

Authors
BU XH CAO XC ZHANG WQ ZHANG RH CLIFFORD T
Citation
Xh. Bu et al., A NEW TETRAAZAMACROCYCLE FUNCTIONALIZED WITH PENDANT PYRIDYL GROUPS -SYNTHESIS AND CRYSTAL-STRUCTURE OF A COPPER(II) COMPLEX OF IS(2-PYRIDYLMETHYL)-1,4,7,10-TETRAAZACYCLODODECANE (L), [CUL]CENTER-DOT(CLO4)(2), Transition metal chemistry, 22(5), 1997, pp. 513-515
Citations number
9
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Transition metal chemistry
ISSN journal
03404285 → ACNP
Volume
22
Issue
5
Year of publication
1997
Pages
513 - 515
Database
ISI
SICI code
0340-4285(1997)22:5<513:ANTFWP>2.0.ZU;2-0
Abstract
The [CuL](ClO4), complex, L = 1,4,7,10-tetrakis(2-pyridylmethyl)-1 ,4, 7,10-tetraazacyclododecane, was prepared in EtOH and characterized. Th e crystal structure of the complex was determined by single-crystal X- ray analysis. The coordination geometry about the copper ion can be de scribed as a strongly distorted octahedron, with Cu-N distances rangin g from 2.01(1)-2.82(1) Angstrom.