CONTROL OF AVERAGE SIZE AND SIZE DISTRIBUTION IN AS-GROWN NANOPARTICLE POLYMER COMPOSITES OF MSE (M = CD OR ZN)

The preparation of CdSe and ZnSe semiconductor nanoparticles in the qu antum size regime (1-5 nm) within a polymer matrix is described. A car efully controlled reaction temperature and suitable choice of solvent is found to have a dramatic effect on the size of the particles produc ed when a soluble pyridyl polymer adduct (a polymer that contains nitr ogen and dimethylcadmium or dimethylzinc) is reacted with H2Se in solu tion. An expected change in colour (absorbance) of the material from b lack through to yellow is observed for cadmium selenide and dark yello w to light yellow for zinc selenide as the particles decrease in size. TEMs reveal that cadmium selenide particles are evenly distributed in the polymer him with a size distribution wider than analogous sulfide preparations recently reported. The CdSe particles exhibit size quant ization and hence a blue shift of the band edge position is observed i n the absorbance and photoacoustic spectra as the reaction temperature is decreased or the polymer solubility is improved. ZnSe nanoparticle growth has been found difficult to control although a change in react ion temperature has an effect on the particle size similar to that for CdSe.