INCLUSION AND SEPARATION OF PICOLINE ISOMERS BY A DIOL HOST COMPOUND

Authors
CAIRA MR HORNE A NASSIMBENI LR TODA F
Citation
Mr. Caira et al., INCLUSION AND SEPARATION OF PICOLINE ISOMERS BY A DIOL HOST COMPOUND, Journal of materials chemistry, 7(10), 1997, pp. 2145-2149
Citations number
22
Categorie Soggetti
Chemistry Physical","Material Science
Journal title
Journal of materials chemistry → ACNP
ISSN journal
09599428
Volume
7
Issue
10
Year of publication
1997
Pages
2145 - 2149
Database
ISI
SICI code
0959-9428(1997)7:10<2145:IASOPI>2.0.ZU;2-D
Abstract
Structures of the inclusion compounds formed between the host compound 1,1-bis(4-hydroxyphenyl)cyclohexane and the isomers of picoline have been elucidated. The activation energies and the kinetics of desolvati on for the complexes have been determined. Competition experiments hav e been performed to investigate which isomer is preferentially enclath rated by the host. Lattice energy calculations explain the results of the competition experiments.