MONO-AND BIS-SILYLATED TELLURIUM REAGENTS IN SILVER-TELLURIDE CLUSTERSYNTHESIS - CHARACTERIZATION OF AG30TE21 AND AG46TE29 COMPLEXES

Authors
CORRIGAN JF FENSKE D
Citation
Jf. Corrigan et D. Fenske, MONO-AND BIS-SILYLATED TELLURIUM REAGENTS IN SILVER-TELLURIDE CLUSTERSYNTHESIS - CHARACTERIZATION OF AG30TE21 AND AG46TE29 COMPLEXES, Chemical communications, (19), 1997, pp. 1837-1838
Citations number
18
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
19
Year of publication
1997
Pages
1837 - 1838
Database
ISI
SICI code
1359-7345(1997):19<1837:MBTRIS>2.0.ZU;2-7
Abstract
AgCl, dissolved in ether solvents with tertiary phosphine ligands, rea cts with a combination of the silylated reagents Te(SiMe3)(2) and Te(R ')SiMe3 (R' = Ph, mes) to yield the cluster complexes [Ag-30(TePh)(12) Te-9(PEt2R)(12)] (R = Et 1a, Ph 1b) and [Ag-46{Te(mes)}(12)Te-17(PEt3) (16)] 2 in good yields; the molecular structures of 1a and 2 are descr ibed.