MODELING THE ACTIVE-SITES OF HETEROGENEOUS TITANIUM-CENTERED EPOXIDATION CATALYSTS WITH SOLUBLE SILSESQUIOXANE ANALOGS

Authors
MASCHMEYER T KLUNDUK MC MARTIN CM SHEPHARD DS THOMAS JM JOHNSON BFG
Citation
T. Maschmeyer et al., MODELING THE ACTIVE-SITES OF HETEROGENEOUS TITANIUM-CENTERED EPOXIDATION CATALYSTS WITH SOLUBLE SILSESQUIOXANE ANALOGS, Chemical communications, (19), 1997, pp. 1847-1848
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
19
Year of publication
1997
Pages
1847 - 1848
Database
ISI
SICI code
1359-7345(1997):19<1847:MTAOHT>2.0.ZU;2-D
Abstract
By synthesising and structurally characterising new soluble titanosils esquioxanes, and by following the dynamics of epoxidation of cyclohexe ne in their presence, the tripodally anchored Ti-IV active sites in Ti -SiO2 heterogeneous catalysts are modelled structurally and catalytica lly.