STOICHIOMETRIC ASSEMBLY OF ](2)LI-6-CENTER-DOT-6HNME(2)CENTER-DOT-2C(6)H(5)ME - A HIGHLY FLUXIONAL ANTIMONY(III) PHOSPHINIDINE COMPLEX CONTAINING ME2NH LIGATION OF LITHIUM

Authors
BESWICK MA GOODMAN JM HARMER CN HOPKINS AD PAVER MA RAITHBY PR WHEATLEY AEH WRIGHT DS
Citation
Ma. Beswick et al., STOICHIOMETRIC ASSEMBLY OF ](2)LI-6-CENTER-DOT-6HNME(2)CENTER-DOT-2C(6)H(5)ME - A HIGHLY FLUXIONAL ANTIMONY(III) PHOSPHINIDINE COMPLEX CONTAINING ME2NH LIGATION OF LITHIUM, Chemical communications, (19), 1997, pp. 1879-1880
Citations number
28
Categorie Soggetti
Chemistry
Journal title
Chemical communications → ACNP
ISSN journal
13597345
Issue
19
Year of publication
1997
Pages
1879 - 1880
Database
ISI
SICI code
1359-7345(1997):19<1879:SAO]>2.0.ZU;2-U
Abstract
All of the Me2NH produced by the reaction of [Sb(NMe2)(3)] with CyP(H) Li(Cy = C6H11) coordinates the Li+ cations of the product [Sb(PCy)(3)] (2)Li-6 . 6HNMe(2) . 2C(6)H(5)Me 1; the complex contains the first exa mple of a group 15 metal phosphinidine anion {[Sb(PR)(3)](3-)}.