P. Nielaba et Jl. Lebowitz, PHASE-TRANSITIONS IN THE MULTICOMPONENT WIDOM-ROWLINSON MODEL AND IN HARD CUBES ON THE BCC LATTICE, Physica. A, 244(1-4), 1997, pp. 278-284
We use Monte Carlo techniques and analytical methods to study the phas
e diagram of the M-component Widom-Rowlinson model on the bce lattice:
there are M species all with the same fugacity = and a nearest-neighb
or hard core exclusion between unlike particles. Simulations show that
for M greater than or equal to 3 there is a ''crystal phase'' for = l
ying between z(c)(M) and z(d)(M) while for z > z(d)(M) there are M dem
ixed phases each consisting mostly of one species. For M = 2 there is
a direct second-order transition from the gas phase to the demixed pha
se while for M greater than or equal to 3 the transition at z(d)(M) ap
pears to be first order putting it in the Potts model universality cla
ss. For M large, Pirogov-Sinai theory gives z(d)(M) similar to M - 2 2/(3M(2)) +.... In the crystal phase the particles preferentially occ
upy one of the sublattices, independent of species, i.e. spatial symme
try but not particle symmetry is broken, For M --> infinity this trans
ition approaches that of the one-component hard cube gas with fugacity
y = zM. We find by direct simulations of such a system a transition a
t y(c) similar or equal to 0.71 which is consistent with the simulatio
n z(c)(M) for large M. This transition appears to be always of the Isi
ng type.