THE DEPOSITION OF NA-BETA''-AL2O3 BY VAPOR-VAPOR REACTION

Citation
Ck. Kuo et al., THE DEPOSITION OF NA-BETA''-AL2O3 BY VAPOR-VAPOR REACTION, Solid state ionics, 100(1-2), 1997, pp. 157-163
Citations number
8
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
ISSN journal
01672738
Volume
100
Issue
1-2
Year of publication
1997
Pages
157 - 163
Database
ISI
SICI code
0167-2738(1997)100:1-2<157:TDONBV>2.0.ZU;2-Q
Abstract
Vapour-deposited overgrowths of Na-beta ''-Al2O3 that grow on beta ''- Al2O3 single-crystal films at 1300-1350 degrees C have been studied by X-ray diffraction and electron microscopy. Overgrowth relationships a re interpreted by matching the oxygen arrays of the deposited and back ground crystal lattice. Free energy calculations reveal the possible v apour-vapour reactions that lead to Na-beta ''-Al2O3 overgrowth format ion.