STEREOSPECIFIC [4-MORPHOLINO-1,3-BUTADIENES AND ALPHA,BETA-UNSATURATED EXOCYCLIC CHROMIUM CARBENE COMPLEXES - PREPARATION OF ENANTIOMERICALLY PURE SPIRO COMPOUNDS(2]REACTION BETWEEN 2)

Authors
BARLUENGA J AZNAR F BARLUENGA S GARCIAGRANDA S ALVAREZRUA C
Citation
J. Barluenga et al., STEREOSPECIFIC [4-MORPHOLINO-1,3-BUTADIENES AND ALPHA,BETA-UNSATURATED EXOCYCLIC CHROMIUM CARBENE COMPLEXES - PREPARATION OF ENANTIOMERICALLY PURE SPIRO COMPOUNDS(2]REACTION BETWEEN 2), Synlett, (9), 1997, pp. 1040-1042
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1997
Pages
1040 - 1042
Database
ISI
SICI code
0936-5214(1997):9<1040:S[AA>2.0.ZU;2-7
Abstract
A stereospecific exoselective [4+2] reaction between alpha,beta unsatu rated exocyclic chromium carbene complexes and 2-amino-1,3 butadienes is described. Its application employing homochiral carbene complexes g ives rise to the optically pure spiro-lactones.