SYNTHESIS OF (-HOMONONACTIC ACID VIA IODOETHERIFICATION())

Authors
KIYOTA H ABE M ONO Y ORITANI T
Citation
H. Kiyota et al., SYNTHESIS OF (-HOMONONACTIC ACID VIA IODOETHERIFICATION()), Synlett, (9), 1997, pp. 1093-1095
Citations number
36
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Synlett → ACNP
ISSN journal
09365214
Issue
9
Year of publication
1997
Pages
1093 - 1095
Database
ISI
SICI code
0936-5214(1997):9<1093:SO(AVI>2.0.ZU;2-S
Abstract
(+)-Homononactic acid, one of the monomers of polynactin, and its 8-ep imer were synthesized. The key step was cis-selective iodoetherificati on of the enone or the alpha-silyloxyolefin intermediates constructed with Wittig-Horner or Julia coupling reactions, respectively.