C. Saucier et al., FIRST EVIDENCE OF ACETALDEHYDE-FLAVANOL CONDENSATION PRODUCTS IN RED WINE, American journal of enology and viticulture, 48(3), 1997, pp. 370-373
A dimeric polyphenolic fraction was purified from a two months old Cab
ernet Sauvignon wine. This fraction was studied by LC-ES-MS. Several p
roducts with a 606 mass corresponding to a dime. of 2 flavanol monomer
units linked by an ethyl bridge were detected. Identification of cate
chin-acetaldehyde dimers was achieved by injection of synthetic dimers
. In addition to retention time, mass spectra were obtained an each pe
ak. By increasing the cone voltage in the electrospray source, specifi
c fragments could be generated which further confirm the structures of
the molecules.