SYNTHESIS, CHARACTERIZATION AND PHOTOPHYSICS OF LUMINESCENT ORGANOGOLD(I) PHOSPHINES

Authors
YAM VWW CHOI SWK
Citation
Vww. Yam et Swk. Choi, SYNTHESIS, CHARACTERIZATION AND PHOTOPHYSICS OF LUMINESCENT ORGANOGOLD(I) PHOSPHINES, Journal of the Chemical Society. Dalton transactions, (14), 1994, pp. 2057-2059
Citations number
19
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Dalton transactions → ACNP
ISSN journal
03009246
Issue
14
Year of publication
1994
Pages
2057 - 2059
Database
ISI
SICI code
0300-9246(1994):14<2057:SCAPOL>2.0.ZU;2-E
Abstract
Reaction of [Au2(dmpm)Cl2] or [Au3(dmmp)Cl3] with an excess of organol ithium reagent LiR in diethyl ether gave [Au2(dmpm)R2] or [Au3(dmmp)R3 ] in high yield [dmpm = MePCH2PMe2; dmmp = Me2PCH2P(Me)CH2PMe2; R = Me or C6H4OMe-p]. These compounds were found to be emissive both in the solid state and in fluid solutions. An excited-state redox potential o f -2.0(1) V vs. sodium chloride saturated calomel electrode has been e stimated for [Au3(dmmp)(C6H4OMe-p)3].