SYNTHETIC AND STRUCTURAL CHARACTERIZATION OF METAL-COMPLEXES OF FERROCENYLACETYLENE - NOVEL DONOR-ACCEPTOR HETEROBIMETALLIC MATERIALS

Citation
Mcb. Colbert et al., SYNTHETIC AND STRUCTURAL CHARACTERIZATION OF METAL-COMPLEXES OF FERROCENYLACETYLENE - NOVEL DONOR-ACCEPTOR HETEROBIMETALLIC MATERIALS, Journal of the Chemical Society. Dalton transactions, (14), 1994, pp. 2215-2216
Citations number
20
Categorie Soggetti
Chemistry Inorganic & Nuclear
ISSN journal
03009246
Issue
14
Year of publication
1994
Pages
2215 - 2216
Database
ISI
SICI code
0300-9246(1994):14<2215:SASCOM>2.0.ZU;2-D
Abstract
Two novel metal (ruthenium or osmium) complexes of ferrocenylacetylene have been synthesised and the crystal structure of [Fe(C5H5){C5H4C=C[ Os(dppm)2Cl]}] [dppm = 1,2-bis(diphenylphosphino)-methane] has been de termined; their solution redox chemistry indicated metal-metal interac tion via the conjugated ligand group.