An electrospray method is used for the conversion of isolated molecule
s of atactic polystyrene of high molar mass in solution to solid, sing
le-molecule particles. With this process it is possible to produce not
only single molecules but also clusters of several molecules. Particl
e size and shape distributions were characterized using scanning force
and scanning electron microscopy. The size of the clusters of more th
an one molecule can be tailored to ones needs by controlling the spray
conditions.