Zx. Fan et al., X-RAY STUDY OF THE HIGHLY ORDERED SMECTIC PHASES OF N-PENTYL-N'-(P-PENTYLOXYPHENYL)PIPERAZINE, Liquid crystals, 17(2), 1994, pp. 235-242
The structures of the highly ordered liquid crystalline smectic phases
of N-pentyl-N'-(p-pentyloxyphenyl)piperazine are identified using X-r
ay diffraction methods. For this compound a phase sequence hexagonal s
mectic B (S(B))-orthorhombic crystalline smectic E (C(E))-monoclinic c
rystalline smectic H (C(H)) is observed for the first time. The change
s in structural symmetry at the phase transitions are discussed.