RADIOLYSIS OF CFCL3 IN METHYLCYCLOHEXANE AND BINARY MATRICES AT LOW-TEMPERATURE

Authors
Citation
Jp. Suwalski, RADIOLYSIS OF CFCL3 IN METHYLCYCLOHEXANE AND BINARY MATRICES AT LOW-TEMPERATURE, Polish Journal of Chemistry, 71(10), 1997, pp. 1425-1435
Citations number
45
Categorie Soggetti
Chemistry
Journal title
ISSN journal
01375083
Volume
71
Issue
10
Year of publication
1997
Pages
1425 - 1435
Database
ISI
SICI code
0137-5083(1997)71:10<1425:ROCIMA>2.0.ZU;2-B
Abstract
Results of pulse and gamma-radiolysis of CFCl3 in methylcyclohexane an d binary matrices methylcyclohexane/iso-pentane at 6-77 K are presente d and discussed. The model of the radical cation scavenging at low tem perature is proposed and discussed and the influence of the ionization energy of the matrix on the electron transfer reaction between radica l cation and scavenger at low temperature is presented.