N. Zabala et al., COUPLING EFFECTS IN THE EXCITATIONS BY AN EXTERNAL ELECTRON-BEAM NEARCLOSE PARTICLES, Physical review. B, Condensed matter, 56(12), 1997, pp. 7623-7635
The energy-loss experienced by swift scanning transmisson electron mic
roscopy electrons is calculated for a target constituted by two spheri
cal particles in the framework of dielectric theory, using bispherical
coordinates. Deviations from the behavior of the isolated sphere are
investigated. The coupling between close particles and its effects on
the energy-loss spectrum is found to depend significantly on the elect
ron trajectory and target situation (particle size and interparticle d
istance). Excitations above the planar surface plasmon energy are foun
d to be the dominant contribution to the loss spectrum for trajectorie
s between the two spheres, while low-energy excitations, under those o
f the isolated sphere, appear for trajectories out of that region. The
different possibilities are analyzed and compared with experimental r
esults for aluminum particles and provisions of recent effective mediu
m theories. The inelastic part of the induced electric field around th
e spheres is also studied showing a very important localization of the
excitation in the space between both particles, even for trajectories
outside that region. The expressions obtained are available for any l
ocal dielectric function.