SYNTHESIS, STRUCTURE AND PROPERTIES OF UNDECATUNGSTOZINCATE CONTAINING 3A ELEMENTS

Authors
YANG QH ZHOU DF DAI HG LIU JF XING Y LIN YH JIA HQ
Citation
Qh. Yang et al., SYNTHESIS, STRUCTURE AND PROPERTIES OF UNDECATUNGSTOZINCATE CONTAINING 3A ELEMENTS, Polyhedron, 16(23), 1997, pp. 3985-3989
Citations number
11
Categorie Soggetti
Chemistry Inorganic & Nuclear",Crystallography
Journal title
Polyhedron → ACNP
ISSN journal
02775387
Volume
16
Issue
23
Year of publication
1997
Pages
3985 - 3989
Database
ISI
SICI code
0277-5387(1997)16:23<3985:SSAPOU>2.0.ZU;2-P
Abstract
New compounds KaHb[ZnW11O39M(H2O)]. xH(2)O (M = Al, Ga or In) were pre pared and characterized by elemental analysis, IR and UV and Al-27 NMR spectroscopy, electrochemistry and X-ray crystallography. In the crys tals of K6H3[ZnW11AlO40]. 9.5H(2)O, the anion is of the alpha-type Keg gin structure with C-s symmetry. The Al and W atoms are statistically distributed in the crystal. (C) 1997 Elsevier Science Ltd.