EFFECT OF PRECURSOR, DISPERSITY AND WATER-VAPOR TREATMENT ON STRUCTURE-INSENSITIVE HYDROGENATION REACTIONS ON RH SILICA/

Authors
RONZON E DELANGEL G
Citation
E. Ronzon et G. Delangel, EFFECT OF PRECURSOR, DISPERSITY AND WATER-VAPOR TREATMENT ON STRUCTURE-INSENSITIVE HYDROGENATION REACTIONS ON RH SILICA/, Reaction kinetics and catalysis letters, 62(1), 1997, pp. 75-81
Citations number
10
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
62
Issue
1
Year of publication
1997
Pages
75 - 81
Database
ISI
SICI code
0133-1736(1997)62:1<75:EOPDAW>2.0.ZU;2-Y
Abstract
The hydrogenation of 2-cyclohexen-1-one and cyclohexene were studied i n liquid phase over Rh/SiO2 catalysts. The turnover frequency for both reactions is independent of the dispersity for each set of catalysts prepared with organic or chloride rhodium precursors. An effect of the precursor was observed: the chlorinated catalysts showed a higher act ivity than the non-chlorinated ones. However, the highest activity was observed when the catalysts were thermally treated with hydrogen satu rated with water vapor (HWV).