KINETICS OF THERMAL-DECOMPOSITION OF DIMETHYLDIOXIRANE IN OXYGEN ATMOSPHERE

Authors
GRABOVSKI SA KAZAKOV DV KABALNOVA NN KHURSAN SL SHERESHOVETS VV
Citation
Sa. Grabovski et al., KINETICS OF THERMAL-DECOMPOSITION OF DIMETHYLDIOXIRANE IN OXYGEN ATMOSPHERE, Reaction kinetics and catalysis letters, 62(1), 1997, pp. 179-183
Citations number
8
Categorie Soggetti
Chemistry Physical
Journal title
Reaction kinetics and catalysis letters → ACNP
ISSN journal
01331736
Volume
62
Issue
1
Year of publication
1997
Pages
179 - 183
Database
ISI
SICI code
0133-1736(1997)62:1<179:KOTODI>2.0.ZU;2-P
Abstract
Dimethyldioxirane decomposition in oxygen atmosphere follows a first-o rder kinetic law. Decomposition rate constant (k, s(-1)) in acetone in the temperature range from 30 to 50 degrees C has been determined as lgk = (7.1 +/- 0.9)-(16.0 +/- 1.4)/theta, theta = 2.303RT kcal/mol.