MONOCHROMATIC NUCLEAR-MAGNETIC-RESONANCE NUTATION SPECTROSCOPY - CORRELATED FLUCTUATIONS OF DIPOLAR COUPLINGS AND ANISOTROPIC CHEMICAL-SHIFTS IN AROMATIC PROTON SYSTEMS

Citation
R. Konrat et al., MONOCHROMATIC NUCLEAR-MAGNETIC-RESONANCE NUTATION SPECTROSCOPY - CORRELATED FLUCTUATIONS OF DIPOLAR COUPLINGS AND ANISOTROPIC CHEMICAL-SHIFTS IN AROMATIC PROTON SYSTEMS, Journal of physical chemistry, 98(31), 1994, pp. 7488-7491
Citations number
14
Categorie Soggetti
Chemistry Physical
ISSN journal
00223654
Volume
98
Issue
31
Year of publication
1994
Pages
7488 - 7491
Database
ISI
SICI code
0022-3654(1994)98:31<7488:MNNS-C>2.0.ZU;2-B
Abstract
A new method to demonstrate the buildup of longitudinal two-spin order in an AX spin system on account of D-CSA cross-correlation is shown. Two-spin order 2I(2)AI(2)X is created by using trains of selective squ are pulses which nutate only one spin of a two-spin system. Moreover, it is demonstrated, by measuring different aromatic compounds, that ar omatic protons are prone to show an anisotropic chemical shift-CSA-ter m-of roughly 4-8 ppm.