Sol-gel chemistry has a great many potential applications in the prepa
ration of unique electrochemical materials, from non-equilibrium trans
ition metal oxides which may be of use as high energy density electrod
es, to high surface area mixed oxides which may possess high proton co
nductivity, to novel composite structures consisting of inorganic gels
in combination with organic electronic and ionic conductors. This pap
er reviews prior work on proton conduction in gel systems and presents
recent work regarding electrode materials prepared by sol-gel methods
and inorganic-organic materials.