A DENDRITE MODEL OF CURRENT INSTABILITY IN RBAG4I5

Citation
Vn. Bondarev et Pv. Pikhitsa, A DENDRITE MODEL OF CURRENT INSTABILITY IN RBAG4I5, Solid state ionics, 70, 1994, pp. 72-76
Citations number
11
Categorie Soggetti
Physics, Condensed Matter","Chemistry Physical
Journal title
ISSN journal
01672738
Volume
70
Year of publication
1994
Part
1
Pages
72 - 76
Database
ISI
SICI code
0167-2738(1994)70:<72:ADMOCI>2.0.ZU;2-Y
Abstract
A theoretical model of the electronic current instability observed exp erimentally by Bredikhin et al. in the cell Ag(-)/RbAg4I5/C(+) at vari ous constant voltages is proposed. The model is based on the concept o f fractal growth of silver dendritic clusters from the Ag(-)/RbAg4I5 i nterface. It is shown that some of the clusters make connections betwe en opposite electrodes at sufficiently large voltages, which leads to stochastic current oscillations. We show that the number of connecting clusters increases as the voltage is raised and therefore current osc illations become more frequent. All experimental dependences on curren t instability are well described within the framework of a mean-field approach to the theory of reversible diffusion-limited aggregation wit hout branching.