HALOGEN ATOM-TRANSFER RADICAL CYCLIZATION OF N-ALLYL-N-BENZYL-2,2-DIHALOAMIDES TO 2-PYRROLIDINONES, PROMOTED BY FE-0-FECL3 OR CUCL-TMEDA

Authors
BENEDETTI M FORTI L GHELFI F PAGNONI UM RONZONI R
Citation
M. Benedetti et al., HALOGEN ATOM-TRANSFER RADICAL CYCLIZATION OF N-ALLYL-N-BENZYL-2,2-DIHALOAMIDES TO 2-PYRROLIDINONES, PROMOTED BY FE-0-FECL3 OR CUCL-TMEDA, Tetrahedron, 53(41), 1997, pp. 14031-14042
Citations number
92
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Tetrahedron → ACNP
ISSN journal
00404020
Volume
53
Issue
41
Year of publication
1997
Pages
14031 - 14042
Database
ISI
SICI code
0040-4020(1997)53:41<14031:HARCON>2.0.ZU;2-7
Abstract
The halogen atom transfer radical cyclization of a N-allyl-N-benzyl-2, 2-dihaloamides to 2-pyrrolidinones has been carried out in high yields under mild conditions, in a reaction promoted by CuCl-TMEDA or Fe-0-F eCl3 in acetonitrile or N,N-dimethylformamide, respectively. (C) 1997 Elsevier Science Ltd.