STUDY OF FACTORS AFFECTING URANIUM STRIPPING FROM DEHMA TOPO SOLVENT BY FACTORIAL DESIGN/

Citation
A. Dahdouh et al., STUDY OF FACTORS AFFECTING URANIUM STRIPPING FROM DEHMA TOPO SOLVENT BY FACTORIAL DESIGN/, Journal of radioanalytical and nuclear chemistry, 221(1-2), 1997, pp. 183-187
Citations number
10
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Analytical","Nuclear Sciences & Tecnology
ISSN journal
02365731
Volume
221
Issue
1-2
Year of publication
1997
Pages
183 - 187
Database
ISI
SICI code
0236-5731(1997)221:1-2<183:SOFAUS>2.0.ZU;2-9
Abstract
Uranium is recovered from wet phosphoric acid by a DEHPA/TOPO mixture. It was found that stripping is the most crucial step in this process. Several studies were undertaken to understand this process in greater depth. This study investigates the main operating variables, mainly c oncentration of phosphoric acid, temperature and concentration of iron on stripping, by the method of factorial design. A mathematical model was developed to represent the data. Another experiment was undertake n to find out the effect of fluoride ion on stripping. The results agr ee well with those of earlier investigations, namely that it is benefi cial to increase the concentration of phosphoric acid and the temperat ure. The increase in fluoride ion concentration leads to an enhancemen t of the stripping distribution ratio.