D. Nesheva et al., BAND AND SUBBAND ABSORPTION OF SE CDSE AMORPHOUS MULTILAYERS/, Philosophical magazine. B. Physics of condensed matter. Structural, electronic, optical and magnetic properties, 70(2), 1994, pp. 205-213
The band and subband absorption in single CdSe layers and pnpn type Se
/CdSe multilayers (MLs) has been measured by the constant photocurrent
method. From studies on the MLs' band absorption the conclusion is re
ached that the photoconductivity of the CdSe sublayers decreases with
both decreasing thickness and evaporation rate. An increase of the Urb
ach edge parameter E(u) from 57 to 80 meV has been obtained on decreas
ing the CdSe sublayer thickness or on increasing the deposition rate.
A 'shoulder' has been observed in the MLs' absorption measured in the
lowest energy region. Indirect transitions from the Se valence band to
the CdSe conduction band have been proposed as a possible explanation
of the shoulder absorption. The observed change in the shoulder posit
ion with changing CdSe sublayer thickness has been attributed to quant
um size effects.