EXPERIMENTAL CONFIRMATION OF AN IRON-GALLIUM MULTIPLE BOND - SYNTHESIS, STRUCTURE, AND BONDING OF A FERROGALLYNE

Authors
SU JR LI XW CRITTENDON RC CAMPANA CF ROBINSON GH
Citation
Jr. Su et al., EXPERIMENTAL CONFIRMATION OF AN IRON-GALLIUM MULTIPLE BOND - SYNTHESIS, STRUCTURE, AND BONDING OF A FERROGALLYNE, Organometallics, 16(21), 1997, pp. 4511-4513
Citations number
24
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
21
Year of publication
1997
Pages
4511 - 4513
Database
ISI
SICI code
0276-7333(1997)16:21<4511:ECOAIM>2.0.ZU;2-B
Abstract
Reaction of disodium tetracarbonylferrate, Na-2[Fe(CO)(4)], with [2, 6 -bis(2,4, 6-triisopropylphenyl)-phenyl]gallium dichloride, (Mes2C6H3) GaCl2 (Mes = 2,4,6-triisopropylphenyl), affords tetracarbonyliron [2, 6-bis(2,4,6-triisopropylphenyl)phenyl]gallyne (CO)(4)Fe drop Ga(C(6)H( 3)Mes(2)), as anaerobically stable yellow prism crystals. The title c ompound offers evidence in support of an iron-gallium triple bond-the first ferrogallyne.