TIN-SUBSTITUTED AND GERMANIUM-SUBSTITUTED ENOL ETHERS FROM FISCHER CARBENE COMPLEXES AND GROUP-14 VINYL DERIVATIVES

Authors
BARLUENGA J GONZALEZ R FANANAS FJ
Citation
J. Barluenga et al., TIN-SUBSTITUTED AND GERMANIUM-SUBSTITUTED ENOL ETHERS FROM FISCHER CARBENE COMPLEXES AND GROUP-14 VINYL DERIVATIVES, Organometallics, 16(21), 1997, pp. 4525-4526
Citations number
31
Categorie Soggetti
Chemistry Inorganic & Nuclear","Chemistry Inorganic & Nuclear
Journal title
Organometallics → ACNP
ISSN journal
02767333
Volume
16
Issue
21
Year of publication
1997
Pages
4525 - 4526
Database
ISI
SICI code
0276-7333(1997)16:21<4525:TAGEEF>2.0.ZU;2-G
Abstract
Trialkyltin- or trialkylgermanium-substituted enol ethers 5 and 2-alko xy-1,3-butadienes 7 have been prepared by the reaction of Fischer carb ene complexes 1-3 and 6 with vinylstannanes and -germanes 4. The openi ng of the metallacyclobutane intermediate by metalloid migration has b een shown by using a 2,2-dideuteriated olefin.