B. Saintmartin et al., APPLICATION OF THE KINETIC-THEORY OF PEPT IDE EPIMERIZATION TO THE DATING OF FOSSILS, Comptes rendus de l'Academie des sciences. Serie 2, Mecanique, physique, chimie, sciences de l'univers, sciences de la terre, 319(2), 1994, pp. 225-230
Non-linear kinetics are an important problem encountered when amino ac
id racemization level is used in the dating of fossils. We tested the
kinetic theory of peptide epimerization [Saint-Martin and Julg, J. Mol
. Struc. (Theochem.), 251, 1991, pp. 375-383] for various non-linear c
ases. Its kinetic relation is fitted to the results from very diverse
fossils and experimental conditions. The fits are particularly good in
the light of the model's simplicity. The consequences for the dating
method are considered.