Due to the electrochemical nature of MIC electrochemical methods are u
seful tools to study reactions at the metal/biofilm interface, investi
gate MIC mechanisms and monitor the onset of MIC and its propagation T
he paper discusses various electrochemical methods - measurement of co
rrosion potential, redox potential, polarization resistance, galvanic
currents. large signal polarization techniques, random potential pulse
method, electrochemical impedance spectrometry, electrochemical relax
ation methods (programmed pulse relaxation, sinusoidal ac relaxation),
electrochemical noise analysis, scanning vibrating electrode techniqu
es (Kelvin probe, vibrating microreference electrode, electrochemical
sensors) - with respect to their applicability and merits for MIC inve
stigations and. monitoring.