INTERACTIONS BETWEEN HEXACYANOFERRATE(II) AND AMINE CR(III) COMPLEXESCOMPARATIVE THERMAL AND PHOTOCHEMICAL STUDY

Authors
STOCHEL G ACHREMACHREMOWICZ J KAROCKI A OSMAN B RYBNIEWSKA D STASICKA Z
Citation
G. Stochel et al., INTERACTIONS BETWEEN HEXACYANOFERRATE(II) AND AMINE CR(III) COMPLEXESCOMPARATIVE THERMAL AND PHOTOCHEMICAL STUDY, Bulletin of the Polish Academy of Sciences. Chemistry, 45(1), 1997, pp. 31-39
Citations number
42
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Polish Academy of Sciences. Chemistry → ACNP
ISSN journal
02397285
Volume
45
Issue
1
Year of publication
1997
Pages
31 - 39
Database
ISI
SICI code
0239-7285(1997)45:1<31:IBHAAC>2.0.ZU;2-7
Abstract
The title systems with [Cr(III)A(n)](m+) (where A(n) = 6NH(3), 3 or 2C l(-)+2en), were found to generate both ion pairs and CN-bridged di-and trinuclear complexes. The dinuclear complexes produced thermally (exc ept for A = NH3) and photochemically are of cis configuration at the C r centre. The dinuclear trans complex is produced from the photolysed Cr(III) complex and [Fe(CN)(6)](4-).