SOLVENT REORGANIZATION ENERGIES FOR THE OUTER-SPHERE ELECTRON-TRANSFER IN THE TRIAD SYSTEM

Authors
NAJBAR J
Citation
J. Najbar, SOLVENT REORGANIZATION ENERGIES FOR THE OUTER-SPHERE ELECTRON-TRANSFER IN THE TRIAD SYSTEM, Bulletin of the Polish Academy of Sciences. Chemistry, 45(1), 1997, pp. 79-97
Citations number
57
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Polish Academy of Sciences. Chemistry → ACNP
ISSN journal
02397285
Volume
45
Issue
1
Year of publication
1997
Pages
79 - 97
Database
ISI
SICI code
0239-7285(1997)45:1<79:SREFTO>2.0.ZU;2-A
Abstract
The potential energy surfaces for the electron transfer processes in s upramolecular triad systems containing three electron donor or electro n acceptor subunits in polar media are given in terms of two solvent p olarization coordinates and reorganization energies. The Marcus reorga nization energies and reorganization energy parameters are investigate d for the transition between neutral state and various charge transfer states using the dielectric continuum approximation.