METAL-ION EFFECT ON RESONANCE RAMAN FREQUENCIES OF BOUND MOLECULAR-OXYGEN IN MANGANESE-(PORPHYRIN)O-2, IRON-(PORPHYRIN)O-2, AND COBALT(PORPHYRIN)O-2 COMPLEXES

Authors
PRONIEWICZ LM
Citation
Lm. Proniewicz, METAL-ION EFFECT ON RESONANCE RAMAN FREQUENCIES OF BOUND MOLECULAR-OXYGEN IN MANGANESE-(PORPHYRIN)O-2, IRON-(PORPHYRIN)O-2, AND COBALT(PORPHYRIN)O-2 COMPLEXES, Bulletin of the Polish Academy of Sciences. Chemistry, 45(1), 1997, pp. 99-108
Citations number
52
Categorie Soggetti
Chemistry
Journal title
Bulletin of the Polish Academy of Sciences. Chemistry → ACNP
ISSN journal
02397285
Volume
45
Issue
1
Year of publication
1997
Pages
99 - 108
Database
ISI
SICI code
0239-7285(1997)45:1<99:MEORRF>2.0.ZU;2-W
Abstract
Resonance Raman (RR) data on five-coordinate manganese-, iron-, and co balt (porphyrin)Oz formed in low temperature matrices are collected. M etal ion effect on dioxygen adduct structures is shown based on charac teristic nu(O-O) and nu(metal-O) frequencies. Formation of side-on and /or end-on structures of coordinated dioxygen is discussed.