J. Jakubko et E. Cernoskova, DIFFERENTIAL THERMAL-ANALYSIS OF THE MIXTURES OF SILICON AND RED LEAD, Journal of thermal analysis, 50(3), 1997, pp. 511-515
There are two different opinions in the literature on the combustion m
echanism of the Si-Pb3O4 system. Differential thermal analysis, X-ray
diffraction and infra-red spectroscopy have been used to examine the t
hermal behaviour of the mixture to characterize its combustion product
s and judge the validity of both proposed reaction paths. It was concl
uded from the results that the Si-Pb3O4 system exhibits rather complic
ated reaction mechanism including both gas-solid and solid-solid (proc
eeding below oxidant decomposition temperature) reactions whose import
ance depends on the fuel content of the mixture.