The photovoltaic (PV) effects from sandwiched porous silicon (PS), fab
ricated using electrochemical etching processes, have been investigate
d. Contacts were made by bonding to semi-transparent coatings of Au vi
a a secondary supportive Al contact. The contribution of the PV effect
s from the junctions of the metal (Au)/n-type and p-type PS, and partl
y from the PS/bulk Si heterojunction, was observed for the visible wav
elength range of light, and under white light of different powers. Som
e optical and electrical characteristics of various PV devices have be
en measured under a range of optical powers. Photovoltages of some of
the PV devices with different preparation conditions were measured as
a function of UV/VIS excitation energies. The polarities of photovolta
ge for both types (n- and p-PS) of device were found to be the same. T
he external quantum efficiencies of the PV devices are also presented.