CRYSTAL-STRUCTURES OF DIBENZO-13-CROWN-4 AND SYM-(2-PICOLYLOXY)DIBENZO-13-CROWN-4

Citation
Nk. Dalley et al., CRYSTAL-STRUCTURES OF DIBENZO-13-CROWN-4 AND SYM-(2-PICOLYLOXY)DIBENZO-13-CROWN-4, Journal of inclusion phenomena and molecular recognition in chemistry, 29(3-4), 1997, pp. 309-321
Citations number
10
Categorie Soggetti
Chemistry,Crystallography
ISSN journal
09230750
Volume
29
Issue
3-4
Year of publication
1997
Pages
309 - 321
Database
ISI
SICI code
0923-0750(1997)29:3-4<309:CODAS>2.0.ZU;2-Q
Abstract
Solid-state structures are determined for two compounds which contain dibenzo-13-crown-4 rings. These include the parent crown ether dibenzo -13-crown-4 and its lariat ether derivative sym-(2-picolyloxy)dibenzo- 13-crown-4. The solid-state structure of dibenzo-13-crown-4 is complic ated by disorder of the carbon atoms in the ethylene and propylene bri dges. The asymmetric unit of the crystal for the lariat ether derivati ve consists of two chemically identical, but crystallographically diff erent, molecules.