A NEW WATER-SOLUBLE CALIXARENE - DROXYCARBONYLMETHOXY)-26,28-DIHYDROXYCALIX[4]ARENE - A THERMODYNAMIC AND SPECTROSCOPIC INVESTIGATION OF ITS PROTON AND COPPER(II) COMPLEXES

Authors
ARENA G BONOMO RP CONTINO A GULINO FG MAGRI A SCIOTTO D
Citation
G. Arena et al., A NEW WATER-SOLUBLE CALIXARENE - DROXYCARBONYLMETHOXY)-26,28-DIHYDROXYCALIX[4]ARENE - A THERMODYNAMIC AND SPECTROSCOPIC INVESTIGATION OF ITS PROTON AND COPPER(II) COMPLEXES, Journal of inclusion phenomena and molecular recognition in chemistry, 29(3-4), 1997, pp. 347-363
Citations number
37
Categorie Soggetti
Chemistry,Crystallography
Journal title
Journal of inclusion phenomena and molecular recognition in chemistry → ACNP
ISSN journal
09230750
Volume
29
Issue
3-4
Year of publication
1997
Pages
347 - 363
Database
ISI
SICI code
0923-0750(1997)29:3-4<347:ANWC-D>2.0.ZU;2-H
Abstract
A new water soluble receptor 5,11,17,23-tetrasulphonato-25,27-di droxy carbonylmethoxy)-26,28-dihydroxycalix[4]arene was synthesized and char acterized and its proton and copper(II) complexes were studied and com pared with the analogous species of the fully carboxylated ligand 5,11 ,17,23-tetrasulphonato ,28-tetrakis(hydroxycarbonylmethoxy)caliz[4]are ne. Delta H and Delta S degrees values are crucial for understanding t he peculiar acid-base properties of the ligand. EPR spectra together w ith the UV-VIS spectral data reveal the coordination stereochemistry o f the copper(II) species.