DEVELOPMENT OF A SIMPLE EXPERIMENTAL-METHOD TO MEASURE INTERPHASE COMPOSITION PROFILES GENERATED BY DIFFUSION IN POLYMERS

Citation
P. Tomba et al., DEVELOPMENT OF A SIMPLE EXPERIMENTAL-METHOD TO MEASURE INTERPHASE COMPOSITION PROFILES GENERATED BY DIFFUSION IN POLYMERS, Journal of polymer science. Part B, Polymer physics, 35(15), 1997, pp. 2435-2445
Citations number
31
Categorie Soggetti
Polymer Sciences
ISSN journal
08876266
Volume
35
Issue
15
Year of publication
1997
Pages
2435 - 2445
Database
ISI
SICI code
0887-6266(1997)35:15<2435:DOASET>2.0.ZU;2-I
Abstract
An experimental method to determine interphase composition profiles in amorphous polymers pairs and polymer-solvent pairs is presented. The method is based on the measurement of dynamic mechanical properties of slender composite beams, and well-established properties of amorphous polymer homogeneous blends and solutions. The method does not require tracers. A simple calibration procedure is included in the descriptio n, and some results for a polystyrene-polystyrene pair are used to ill ustrate the method application. (C) 1997 John Wiley & Sons, Inc.