Clinical performance of light-curing composite restorations is greatly
influenced by the quality of the curing light. Currently used photopo
lymerization units have some important drawbacks, such as decreasing l
ight output with time and distance, which results in a relatively low
degree of conversion and shallow depth of cure, particularly of darker
shades. Experiments with continuous argon laser polymerization showed
overheating of the composite sample, as well as increased shrinkage o
f the material. In this study, a pulsed laser, set at 468 nm (the maxi
mum of the camphorquinone absorption coefficient), with 20-ns pulse du
ration, repetition rate of 10 Hz and energy of 10 mJ per pulse, was us
ed as a light source. The aim of the study was to evaluate the effect
of polymerization of light and dark shades of three different hybrid c
omposites cured by pulsed laser at the surface and at 3.0 mm depth. Th
e degree of conversion was measured by Fourier transform infrared spec
troscopy (FTIR). Applying pulsed blue laser, significantly better resu
lts were obtained for both shades compared to standard polymerization
values. Very weak dependence of the degree of conversion, between the
surface measurements and those at 3.0 mm, were observed in the case of
pulsed laser polymerization due to the piercing nanopulses and the mo
nochromatic light at 468 nm. (C) 1997 Published by Elsevier Science Li
mited. All rights reserved.