DIELECTRIC-SPECTROSCOPY OF BINARY-LIQUID MIXTURES OF METHANOL WITH MORPHOLINE, PYRROLIDINE AND SOME OF THEIR DERIVATIVES

Authors
SYAL VK BECKER U ELSEBROCK R STOCKHAUSEN M
Citation
Vk. Syal et al., DIELECTRIC-SPECTROSCOPY OF BINARY-LIQUID MIXTURES OF METHANOL WITH MORPHOLINE, PYRROLIDINE AND SOME OF THEIR DERIVATIVES, Zeitschrift fur Naturforschung. A, A journal of physical sciences, 52(8-9), 1997, pp. 675-677
Citations number
3
Categorie Soggetti
Chemistry Physical",Physics
Journal title
Zeitschrift fur Naturforschung. A, A journal of physical sciences → ACNP
ISSN journal
09320784
Volume
52
Issue
8-9
Year of publication
1997
Pages
675 - 677
Database
ISI
SICI code
0932-0784(1997)52:8-9<675:DOBMOM>2.0.ZU;2-S
Abstract
Dielectric spectra (up to 72 GHz) have been measured at 20 degrees C f or mixtures of methanol and one of the following substances: morpholin e, N-methyl morpholine, N-cyano morpholine, pyrrolidine and N-cyano py rrolidine. The composition dependence of the relaxation parameters sho ws close similarities for the morpholines and, on the other hand, for the pyrrolidines, which indicates that a structure breaking effect on methanol is exerted by the former but not by the latter group of subst ances.