CATALYSIS OF HYDROSILYLATION .31. FUNCTIONALIZATION OF POLY(METHYLHYDRO)SILOXANES VIA HYDROSILYLATION OF ALLYL DERIVATIVES

Authors
MARCINIEC B GULINSKI J KOPYLOVA L MACIEJEWSKI H GRUNDWALDWYSPIANSKA M LEWANDOWSKI M
Citation
B. Marciniec et al., CATALYSIS OF HYDROSILYLATION .31. FUNCTIONALIZATION OF POLY(METHYLHYDRO)SILOXANES VIA HYDROSILYLATION OF ALLYL DERIVATIVES, Applied organometallic chemistry, 11(10-11), 1997, pp. 843-849
Citations number
21
Categorie Soggetti
Chemistry Applied","Chemistry Inorganic & Nuclear
Journal title
Applied organometallic chemistry → ACNP
ISSN journal
02682605
Volume
11
Issue
10-11
Year of publication
1997
Pages
843 - 849
Database
ISI
SICI code
0268-2605(1997)11:10-11<843:COH.FO>2.0.ZU;2-Y
Abstract
The synthesis of functional poly(methylhydro)siloxanes has been succes sfully performed by effective quantitative hydrosilylation of allyl de rivatives (allyl phenyl ether, allyl glycidyl ether, allyl methacrylat e, allyl chloride, allylamine) and 1-octene with poly(methylhydro)silo xanes catalyzed by platinum [PtCl2(PPh3)(2), H2PtCl6-cyclohexanone] an d ruthenium (Ru-3(CO)(12)) complexes, The products were isolated and c haracterized by H-1 NMR, FT IR and GPC methods and can be regarded as examples of well-defined functionalized polysiloxanes with various pra ctical applications. (C) 1997 John Wiley & Sons, Ltd.