DIMETHYLSULFONIUM FLUOREN-9-IDE - SOLUTION STRUCTURE AND DYNAMIC BEHAVIOR OF A SEMI-STABILIZED SULFONIUM YLIDE

Authors
AGGARWAL VK SCHADE S TAYLOR B
Citation
Vk. Aggarwal et al., DIMETHYLSULFONIUM FLUOREN-9-IDE - SOLUTION STRUCTURE AND DYNAMIC BEHAVIOR OF A SEMI-STABILIZED SULFONIUM YLIDE, Journal of the Chemical Society. Perkin transactions. I, (19), 1997, pp. 2811-2813
Citations number
21
Categorie Soggetti
Chemistry Inorganic & Nuclear
Journal title
Journal of the Chemical Society. Perkin transactions. I → ACNP
ISSN journal
0300922X
Issue
19
Year of publication
1997
Pages
2811 - 2813
Database
ISI
SICI code
0300-922X(1997):19<2811:DF-SSA>2.0.ZU;2-G
Abstract
The semi-stabilised ylide, dimethylsulfonium fluoren-9-ide, has been s tudied by variable temperature NMR and found to adopt a conformation i n which the filled orbital on carbon is perpendicular to the lone pair on sulfur. The rotational barrier (Delta G(double dagger)) around the ylide C-S bond is found to be 42.0 +/- 1.0 kJ mol(-1).