DODECYL DODECANAMIDE AS A MODEL FOR THE STUDY OF POLYAMIDE N-CHLORINATION - UNUSUAL BEHAVIORS OF THE REACTION SYSTEM

Authors
GIRARDON V TESSIER M MARECHAL E
Citation
V. Girardon et al., DODECYL DODECANAMIDE AS A MODEL FOR THE STUDY OF POLYAMIDE N-CHLORINATION - UNUSUAL BEHAVIORS OF THE REACTION SYSTEM, Macromolecular symposia, 122, 1997, pp. 313-318
Citations number
14
Categorie Soggetti
Polymer Sciences
Journal title
Macromolecular symposia → ACNP
ISSN journal
10221360
Volume
122
Year of publication
1997
Pages
313 - 318
Database
ISI
SICI code
1022-1360(1997)122:<313:DDAAMF>2.0.ZU;2-F
Abstract
The N-chlorination of dodecyl dodecanamide (DDA) by ter-butyl hypochlo rite (tBuOCl) was carried out at 25 degrees C in methylene chloride. T he conversion is determined by H-1-NMR and iodometric titrations of N- chlorinated DDA (N-Cl DDA). Curves of conversion-time plots present si ngular profiles whose shapes are strongly depending on the reagent and product concentrations.